The Chronicles of the Chronicle Flask: 2018

As has become traditional, I’m finishing off this year with a round-up of 2018’s posts. It’s been a good year: a few health scares which turned out to be nothing much to worry about, one which turned out to be a genuine danger, a couple of cool experiments and some spectacular shiny balls. So without further ado, here we go…

Things were a bit hectic at the start of this year (fiction writing was happening) and as a result January was quiet on the blog. But not on the Facebook page, where I posted a couple of general reminders about the silliness of alkaline diets which absolutely exploded, achieving some 4,000 shares and a reach (so Facebook tells me anyway) of over half a million people. Wow. And then I posted a funny thing about laundry symbols which went almost as wild. It’s a strange world.

February featured BPA: an additive in many plastics.

In February I wrote a piece about BPA (Bisphenol A), which was the chemical scare of the day. There’s always one around January/February time. It’s our penance for daring to enjoy Christmas. Anyway, BPA is a chemical in many plastics, and of course plastic waste had become – and remains – a hot topic. BPA is also used in a number of other things, not least the heat sensitive paper used to produce some shopping receipts. It’s not a harmless substance by any means, but it won’t surprise anyone to learn that the risks had, as is usually the case, been massively overstated. In a report, the European Food Safety Authority said that the health concern for BPA is low at their estimated levels of exposure. In other words, unless you’re actually working with it – in which case you should have received safety training – there’s no need to be concerned.

In March I recorded an episode for the A Dash of Science podcast, and I went on to write a post about VARD, which stands for Verify, Author, Reasonableness and Date. It’s my quick and easy way of fact-checking online information – an increasingly important skill these days. Check out the post for more info.

April ended up being all about dairy and vitamin D.

April was all about dairy after a flare-up on Twitter on the topic, and went on to talk about vitamin D. The bottom line is that everyone in the UK should be taking a small vitamin D supplement between about October and March, because northern Europeans simply can’t make vitamin Din their skin during these months (well, unless they travel nearer to the equator), and it’s not a nutrient we can easily get from our food. Are you taking yours?

May featured fish tanks, following a widely reported story about a fish-owner who cleaned out his tank and managed to release a deadly toxin that poisoned his entire family. Whoops. It turns that this was, and is, a real risk – so if you keep fish and you’ve never heard of this before, do have a read!

In June I wrote about strawberries, and did a neat experiment to show that strawberries could be used to make pH indicator. Who knew? You do, now! Check it out if you’re looking for some chemistry to amuse yourself over the holidays (I mean, who isn’t?). Did you know you can make indicators from the leaves of Christmas poinsettia plants, too?

Slime turned up again in July. And December. And will probably keep on rearing its slimy head.

July brought a subject which has turned up again recently: slime. I wrote about slime in 2017, too. It’s the gift that keeps on giving. This time it flared up because the consumer magazine and organisation Which? kept promoting research that, they claimed, showed that slime toys contain dangerous levels of borax. It’s all rather questionable, since it’s not really clear which safety guidelines they’re applying and whether they’re appropriate for slime toys. Plus, the limits that I was able to find are migration limits. In other words, it’s not appropriate to measure the total borax content of the slime and declare it dangerous – they should be looking at the amount of borax which is absorbed during normal use. Unless your child is eating slime (don’t let them do that), they’re never going to absorb enough borax to do them any harm. In other words, it’s a storm in a slimepot.

August was all about carbon dioxide, after a heatwave spread across Europe and there was, bizarrely, a carbon dioxide shortage which had an impact on all sorts of things from fizzy drinks to online shopping deliveries. It ended up being a long-ish post which spanned everything from the formation of the Earth, the discovery of carbon dioxide, fertilisers and environmental concerns.

September featured shiny, silver balls.

In September I turned my attention to a chemical reaction which is still to this day used to coat the inside of glass decorations with a thin layer of reflective silver, and has connections with biochemistry, physics and astronomy. Check it out for some pretty pictures of silver balls, and my silver nitrate-stained fingers.

In October I was lucky enough to go on a ‘fungi forage’ and so, naturally, I ended up writing all about mushrooms. Did you know that a certain type of mushroom can be used to make writing ink? Or that some mushrooms change colour when they’re damaged? No? You should go back and read that post, then! (And going back to April for a moment, certain mushrooms are one of the few sources of vitamin D.)

Finally, November ended up being all about water, marking the 235th anniversary of the day that Antoine Lavoisier formally declared water to be a compound. It went into the history of water, how it was proven to have the formula H2O, and I even did an experiment to split water into hydrogen and oxygen in my kitchen – did you know that was possible? It is!

As December neared, the research for my water piece led me to suggest to Andy Brunning of Compound Interest that this year’s Chemistry Advent might feature scientists from the last 24 decades of chemistry, starting in the 1780s (with Lavoisier and Paulze) and moving forward to the current day. This turned out to be a fantastic project, featuring lots of familiar and not quite so-familiar scientists. Do have a look if you didn’t follow along during December.

And that’s it for this year. I hope it’s been a good one for all my readers, and I wish you peace and prosperity in 2019! Suggestions for the traditional January Health Scare, anyone? (Let’s hope it’s not slime again, I’m getting really tired of that one now…)

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A tale of chemistry, biochemistry, physics and astronomy – and shiny, silver balls

A new school term has started here, and for me this year that’s meant more chemistry experiments – hurrah!

Okay, actually round-bottomed flasks

The other day it was time for the famous Tollens’ reaction. For those that don’t know, this involves a mixture of silver nitrate, sodium hydroxide and ammonia (which has to be freshly made every time as it doesn’t keep). Combine this concoction with an aldehyde in a glass container and warm it up a bit and it forms a beautiful silver layer on the glass. Check out my lovely silver balls!

This reaction is handy for chemists because the silver mirror only appears with aldehydes and not with other, similar molecules (such as ketones). It works because aldehydes are readily oxidised or, looking at it the other way round, the silver ions (Ag+) are readily reduced by the aldehyde to form silver metal (Ag) – check out this Compound Interest graphic for a bit more detail.

But this is not just the story of an interesting little experiment for chemists. No, this is a story of chemistry, biochemistry, physics, astronomy, and artisan glass bauble producers. Ready? Let’s get started!

Bernhard Tollens (click for link to image source)

The reaction is named after Bernhard Tollens, a German chemist who was born in the mid-19th century. It’s one of those odd situations where everyone – well, everyone who’s studied A level Chemistry anyway – knows the name, but hardly anyone seems to have any idea who the person was.

Tollens went to school in Hamburg, Germany, and his science teacher was Karl Möbius. No, not the Möbius strip inventor (that was August Möbius): Karl Möbius was a zoologist and a pioneer in the field of ecology. He must have inspired the young Tollens to pursue a scientific career, because after he graduated Tollens first completed an apprenticeship at a pharmacy before going on to study chemistry at Friedrich Wöhler’s laboratory in Göttingen. If Wöhler’s name seems familiar it’s because he was the co-discoverer of  beryllium and silicon – without which the electronics I’m using to write this article probably wouldn’t exist.

After he obtained his PhD Tollens worked at a bronze factory, but it wasn’t long before he left to begin working with none other than Emil Erlenmeyer – yes, he of the Erlenmeyer flask, otherwise known as… the conical flask. (I’ve finally managed to get around to mentioning the piece of glassware from which this blog takes its name!)

It seems though that Tollens had itchy feet, as he didn’t stay with Erlenmeyer for long, either. He worked in Paris and Portugal before eventually returning to Göttingen in 1872 to work on carbohydrates, going on to discover the structures of several sugars.

Table sugar is sucrose, which doesn’t produce a silver mirror with Tollens’ reagent

As readers of this blog will know, the term “sugar” often gets horribly misused by, well, almost everyone. It’s a broad term which very generally refers to carbon-based molecules containing groups of O-H and C=O atoms. Most significant to this story are the sugars called monosaccharides and disaccharides. The two most famous monosaccharides are fructose, or “fruit sugar”, and glucose. On the other hand sucrose, or “table sugar”, is a disaccharide.

All of the monosaccharides will produce a positive result with Tollens’ reagent (even when their structures don’t appear to contain an aldehyde group – this gets a bit complicated but check out this link if you’re interested). However, sucrose does not. Which means that Tollens’ reagent is quick and easy test that can be used to distinguish between glucose and sucrose.

Laboratory Dewar flask with silver mirror surface

And it’s not just useful for identifying sugars. Tollens’ reagent, or a variant of it, can also be used to create a high-quality mirror surface. Until the 1900s, if you wanted to make a mirror you had to apply a thin foil of an alloy – called “tain” – to the back of a piece of glass. It’s difficult to get a really good finish with this method, especially if you’re trying to create a mirror on anything other than a perfectly flat surface. If you wanted a mirrored flask, say to reduce heat radiation, this was tricky. Plus it required quite a lot of silver, which was expensive and made the finished item quite heavy.

Which was why the German chemist Justus von Liebig (yep, the one behind the Liebig condenser) developed a process for depositing a thin layer of pure silver on glass in 1835. After some tweaking and refining this was perfected into a method which bears a lot of resemblance to the Tollens’ reaction: a diamminesilver(I) solution is mixed with glucose and sprayed onto the surface of the glass, where the silver ions are reduced to elemental silver. This process ticked a lot of boxes: not only did it produce a high-quality finish, but it also used such a tiny quantity of silver that it was really cheap.

And it turned out to be useful for more than just laboratory glassware. The German astronomer Carl August von Steinheil and French doctor Leon Foucault soon began to use it to make telescope mirrors: for the first time astronomers had cheap, lightweight mirrors that reflected far more light than their old mirrors had ever done.

People also noticed how pretty the effect was: German artisans began to make Christmas tree decorations by pouring silver nitrate into glass spheres, followed by ammonia and finally a glucose solution – producing beautiful silver baubles which were exported all over the world, including to Britain.

These days, silvering is done by vacuum deposition, which produces an even more perfect surface, but you just can’t beat the magic of watching the inside of a test tube or a flask turning into a beautiful, shiny mirror.

Speaking of which, according to @MaChemGuy on Twitter, this is the perfect, foolproof, silver mirror method:
° Place 5 cm³ 0.1 mol dm⁻³ AgNO₃(aq) in a test tube.
° Add concentrated NH₃ dropwise untill the precipitate dissolves. (About 3 drops.)
° Add a spatula of glucose and dissolve.
° Plunge test-tube into freshly boiled water.

Silver nitrate stains the skin – wear gloves!

One word of warning: be careful with the silver nitrate and wear gloves. Else, like me, you might end up with brown stains on your hands that are still there three days later…

Like the Chronicle Flask’s Facebook page for regular updates, or follow @chronicleflask on Twitter. All content is © Kat Day 2018. You may share or link to anything here, but you must reference this site if you do.

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The Chronicle Flask’s festive chemistry quiz!

Tis the season to be jolly! And also for lots of blog posts and articles about the science of christmas, like this one, and this one, and this one, and even this one (which is from last year, but it’s jolly good).

But here’s the question: have you been paying attention? Well, have you? Time to find out with The Chronicle Flask’s festive quiz! I haven’t figured out how to make this interactive. You’ll have to, I don’t know, use a pen and paper or something.

Arbol_de_navidad_con_adornos_de_personajesQuestion 1)
Which scientist invented a chemical test that can be used to coat the inside of baubles with silver?
a) Bernhard Tollens
b) Karl Möbius
c) Emil Erlenmeyer

Question 2)
Reindeer eat moss which contains arachidonic acid… but why is that beneficial to them?
a) a laxative
b) an anti-freeze
c) a spider repellant

1280px-ChristmasCrackers_2Question 3)
Which chemical makes crackers and party poppers go crack?
a) gunpowder
b) silver fulminate
c) nitrogen triiodide

640px-Glass_of_champagneQuestion 4)
We all like a glass of champagne at this time of year, but what’s in the bubbles?
a) carbon dioxide
b) nitrogen
c) oxgyen

Question 5)
What’s the key ingredient in those lovely bath salts you bought for your grandma?
a) calcium carbonate
b) magnesium sulfate
c) citric acid

The Bird - 2007Question 6)
Which chemical reaction is responsible for both perfectly browned biscuits and crispy, golden turkey?
a) Maillard reaction
b) Hodge reaction
c) Caramel reaction

Question 7)
Sucrose-rodmodelWhere are you most likely to find this molecule at this time of year?
a) in a roast beef joint
b) in the wrapping paper
c) in the christmas cake

Question 8)
Let it snow, let it snow, let it snow… but which fact about (pure) water is true?
a) It glows when exposed to ultraviolet light
b) It expands as it freezes
c) It’s a good conductor of electricity

Ethanol-3D-ballsQuestion 9)
Where are you likely to find this molecule on New Year’s Eve?
a) in a champagne bottle
b) in the party poppers
c) in the ‘first foot’ coal

OperaSydney-Fuegos2006-342289398Question 10)
Who doesn’t love a firework or two on New Years Eve?  But which element is most commonly used to produce the colour green?
a) magnesium
b) sodium
c) barium

(Answers below…)

1a) Bernhard Tollens (but his science teacher was Karl Möbius).
2b) It’s a natural anti-freeze.
3b) Silver fulminate (it always surprises me how many people guess gunpowder. That would be exciting).
4a) carbon dioxide.
5b) magnesium sulfate which, funnily enough, also causes ‘hard’ water.
6a) the Maillard reaction, although Hodge did establish the mechanism.
7c) In the cake – it’s sucrose (table sugar).
8b) it expands as it freezes and is thus less dense than liquid water (which is why ice floats). We take this for granted, but most things contract (and become more dense) as they turn from liquid to solid. You should be grateful – live probably wouldn’t have evolved without this peculiar behaviour.
9a) In the champagne – it’s ethanol (or ‘alcohol’ in everyday parlance).
10c) barium – copper produces green flames too, but barium salts are more commonly used in fireworks.

So how did you do?
Less than 4: D, for deuterium. It’s heavy hydrogen and it’s used to slow things down. Enough said.
4-6: You get a C, by which I mean carbon. Have another slice of coal.
7-8: You’ve clearly been paying attention. B for boring, I mean boron.
9-10: Au-ren’t you clever? Chemistry champion!

Happy New Year everyone! 🙂