Something about sugar (free)

Blenheim Flower Show

The Blenheim Flower Show

Last month I went to the Blenheim Flower Show. I hadn’t been before, and I wasn’t quite sure what to expect. In my head I was imagining rows and rows of flowers with a sort of maze-like path through them. I have no idea why, possibly I’ve been doing too much Wizard of Oz (this is not a euphemism).

Perhaps not surprisingly it wasn’t like that at all. In fact the flowers were confined to a couple of easily-avoidable tents, leaving me to wander around stalls selling everything from jewellery to space-saving furniture, chat to the jolly interesting chaps giving a bee-keeping demonstration and scrounge free samples from the food tent.

And it was in the food tent that I came across the Raw Chocolate Pie stall. Sounds good doesn’t it? They’ve combined some very appealing words there. Anyway, the ladies on the stall were very nice and gave me some pieces to taste, and it was indeed scrummy, and sweet. I mention this because in huge letters across the top of the stall were the words “sugar free”. Hm, I thought. They had already told me that the ‘pies’ (actually more like chocolatey lumps) were made with raw cacao beans. Now, I’m a fan of dark chocolate and I’ve tasted 90% cocoa chocolate. It’s bitter. Bitter with a capital bit. It also has a sort of powdery texture due to the low fat content, and this had neither quality.

“So,” I said conversationally, “what’s it sweetened with?”

“Agave nectar,” came the reply.

thefoodofthegodsAt this point I’d heard of agave nectar but I wasn’t really sure what it actually was, so I simply nodded and bought a bar of nut pie. I intended to bring it home and investigate it properly, but it was hot and it got a bit melty, so I was forced to eat it at lunchtime. I took a picture of the wrapper though.

See how it says “sugar free” right there at the top? They are big on this claim. It says sugar free all over the Living Food raw chocolate pie website too.

What would you imagine that means?

It’s a pertinent question. Sugar is one of those words, like ‘salt‘ and ‘alcohol‘, which has a subtly different meaning in chemistry than it does in everyday speech. For chemists these are groups of compounds, but if you read “add pinch of salt” in a recipe book you don’t wonder whether to add sodium chloride or the copper sulfate from your child’s chemistry set. Likewise, if a bottle of wine claims to be 14% alcohol you don’t ponder whether it’s safe to drink or whether you should save it for paint stripper. (Unless, that is, it’s very cheap wine indeed.)

No, in everyday speech we know that salt means sodium chloride, alcohol means ethanol and sugar means, er… sugar means…

Sucrose

Sucrose

This is where it gets a bit sticky. Because there’s more than one sugar that we eat on a regular basis. The white, or sometimes brown, stuff that people bake with and plop into their hot beverages is mainly sucrose. It’s also called ‘table sugar’, or sometimes ‘cane sugar’ or ‘beet sugar’, because those are the plants from which it’s extracted.

Raw chocolate pies haven’t been made with cane/beet sugar, so they might be able to truthfully claim to be sucrose-free. But sugar-free? We-ell…

180px-Glucose_chain_structure

Glucose

The other two sugars that we’re probably most familiar with are glucose, which is the fuel our cells use for energy during respiration, and fructose, which is found in plants and which, like glucose, can be absorbed directly into the bloodstream.

200px-Skeletal_Structure_of_D-Fructose

Fructose

So fructose is found in plants. In fact, fructose is often found in plants chemically bonded to glucose. To make…. sucrose.

So in short:
glucose + fructose = sucrose

And they’re all sugars, and we eat them all on a fairly regular basis. Our bodies break up sucrose into units of glucose and fructose during digestion, and it’s fair to say that none of them are particularly healthy if consumed in large quantities. They’re calorific, bad for your teeth, nutrient-free (other than as an energy source), and regularly eating large quantities of sugar (of any kind) puts you at a greater risk of type II diabetes.

So what’s in agave nectar? Well it comes from a plant, the agave plant, so if you’ve been paying attention that should give you a clue. Yep, it’s packed full of fructose. Which is a sugar. In fact, there are a lot of health concerns around fructose. You may have heard of high fructose corn syrup, or HFCS. This stuff is controversial, with claims that it contributes to obesity, cardiovascular disease, diabetes and non-alcoholic fatty liver disease. Other groups claim these links are unproven, and it’s no worse than any other type of sugar. These groups are mainly people that make and sell high fructose corn syrup, so draw your own conclusions.

Back to agave nectar or, more accurately, syrup. It actually has considerably more fructose than high fructose corn syrup. So bearing all that in mind, is it a healthy alternative? Er, almost certainly not.

Is it correct to call something that’s sweetened with agave ‘sugar free’?

I had a little poke around the Food Standards website. It was something of a slog, but as far as I can work out, the word ‘sugar’ in an ingredients list specifically refers to sucrose. So, you don’t have to list ‘sugar’ in the ingredients list if sucrose isn’t specifically used as an ingredient. But what about the term ‘sugar-free’?

I struggled to find a clear definition of this term on the FSA website, which was a bit annoying (see update below). The best source I can come up with is The Sugar Association, which I’m fairly sure is an American site and so the information quoted wouldn’t apply to a British producer. Still, it’s the best I’ve got, and I’d put money on the rules being similar if not quite identical. This is what they say:

‘“Sugar Free”: Less than 0.5 g sugars per reference amount and per labeled serving (or for meals and main dishes, less than 0.5 g per labeled serving). No ingredient that is a sugar or generally understood to contain sugars except as noted below(*)’ (sic)

The “as noted below” refers to sugar alcohols. These are things like xylitol, mannitol and sorbitol. They often turn up in things like chewing gum. Fructose, at the risk of stating the obvious, is not a sugar alcohol.

There was no percentage composition on the raw chocolate pie wrapper, but just from the taste I’m pretty certain it had more than 0.5 g of sugars (i.e. fructose) per serving. Nothing is that sweet without sugars, unless it also contains artificial sweeteners (which aren’t listed as an ingredient).

I did find this on the Food Standards website:

“To sell food and drink products, the label must be: […] not misleading”

Sugar-free Coke?

Sugar-free Coke?

Is calling something sweetened with a high-fructose syrup (because that’s what agave ‘nectar’ is) misleading? I’m afraid to say that, although I did very much enjoy my nut pie snack, I think it is. By the logic that seems to be being applied here, Coca Cola could use high fructose corn syrup as an sweetener and label their red non-diet bottles and cans as sugar-free, which would be patently ridiculous.

It’s a shame really, because Living Food have a nice product. They just need to get their labelling sorted out.

—-

Update 4th August 2014
After I wrote this I continued my quest to find a proper definition of “sugar-free”. I tried the Food Standards Agency, who sent me to Defra, who ignored me. So I went back to the FSA, who eventually sent me this link. It’s a very interesting document, clarifying and giving examples of how EU Regulation No. 1924/2006, which is all about nutrition and health claims on food, should be applied. On page 70 it says:

‘”The Regulation does […] define any product with no more than 0.5g of sugar per 100ml or per 100g as “sugar free”’

And so conversely, anything with more than 0.5 g of sugar per 100 g as NOT sugar-free. (The official definitions of sugar-free, low-sugar and no added sugar can all be found in the Annex, on page 14, of EU Regulation No. 1924/2006). What still wasn’t entirely clear was exactly what’s meant by ‘sugar’. But now I had somewhere to start. Rooting through EU Regulation No. 1924/2006 I found that it referred to Directive 90/496/EEC for definitions. And there, finally, I got my answer, in Article 1, page 4:

“‘sugars’ means all monosaccharides and disaccharides present in food, but excludes polyols”

Voilà! Fructose is a monosaccharide, and therefore if your product has more than 0.5 g of fructose per 100 g, then it cannot accurately be labelled sugar-free.

I can’t prove this is the case for the Raw Chocolate Pies, since I my testing involves tasting two samples. But if it looks like a duck, and quacks like a duck, it’s probably a very sugary duck.

The question of ‘no added sugar’ may be somewhat irrelevant, since they’re not making this claim, but I think it’s illuminating. If agave syrup has been added then “no added sugar” can’t even be used, since (from regulation (EC) No. 1924/2006):

“A claim stating that sugars have not been added to a food, and any claim likely to have the same meaning for the consumer, may only be made where the product does not contain any added mono- or disaccharides or any other food used for its sweetening properties.”

So that’s the end of the journey, really. You can only call something sugar-free if there’s no sugar in it, and that includes fructose (‘fruit sugar’), glucose and sucrose (‘table’ sugar). Foods sweetened with agave, which contains fructose, aren’t sugar-free, unless they have only the tiniest amount – less than 0.5 g per 100 g – added.

Advertisements

Perpetual motion in chemistry?

Today 25 Inventions Are The Best Thing Since Sliced Bread appeared in my Facebook feed. I’m a bit of a sucker for gadgety things, so I clicked through and had a look.

The ironing board mirror didn’t inspire me (given my normal lack of love for ironing boards, this seems like a short step to 7 years bad luck), but I wish my local council would invest in hourglass traffic lights, I want to know where I can buy universal wrapping paper and the pizza scissors are going on my Christmas list.

useful-inventions-36And then I got to item number 25, the reusable candle.

Hm.

As you’ll see if you follow the link, the following text sits under the picture: “Image credits: Benjamin Shine (h/t: boredpanda via remarkably)”

The first link, the one that mentions Benjamin Shine, links to a page describing him as a British artist and designer. I hadn’t heard of him, so I reached for Google (other search engines are, apparently, available). I quickly found his webpage. The candle is indeed listed there, and it even has a name. It’s called the Rekindle. Which is quite a cool name, although it’s just possible Amazon might have an issue with it.

Well, Mr Shine might be a talented designer, but I fear his science is a tad shaky (assuming it’s a real design and not some kind of clever joke, in which case my apologies). This invention is the chemistry equivalent of a perpetual motion machine.

In case you’ve never heard of a perpetual motion machine, allow me to explain: it’s a hypothetical machine that continues indefinitely without any source of energy. If you just think about it for a moment you quickly realise that such a thing can’t be possible, because if it were half the world wouldn’t be squabbling over ever-decreasing oil supplies.

It doesn’t, and cannot, work because you can’t create or destroy energy (that’s the first law of thermodynamics. The second law is that we don’t talk about the first law. Perpetual motion machines violate that one too). If a machine is doing work, it will always lose some energy to its surroundings, due to friction and so on. In short, machines always produce less energy than you have to put in to start with.

candle-flame-1-ajhdNow Einstein, who was a terribly clever chap (and jolly good at Maths whilst at school despite the apocryphal story) came up with the famous equation: E=mc2, which rather elegantly links energy with matter. Thus, laws that apply to energy also apply to matter. If you can’t create or destroy energy, you can’t create or destroy matter, either. You can change it from one form to another, and under certain circumstances matter can be converted into energy, but you can’t actually create or destroy it. This is why your chemistry teacher made you balance all those flipping equations at school. It’s also why magic doesn’t work in real life (sorry Harry).

What has this got to do with candles? Well, what is the energy source in a candle? There has to be one, it’s producing heat and light. Here’s a clue: it’s not, as many people think, the wick.

No, it’s the wax. Depending on the source, waxes are basically hydrocarbons. Some of them have a bit of oxygen thrown into the mix as well, but essentially the equation is:

wax + oxygen –> carbon dioxide + water

So, you see, although Mr Shine’s design is interesting, the photos are I’m afraid rather misleading. Although a bit of wax might drip down the sides of a candle as you use it, if you burn it right down there definitely won’t be enough left to fill the container Benjamin Shine has shown filling up in the bottom section of his candle stick. You can’t have your cake and eat it, and you can’t have your candle and burn it too. 

“Oh ye seekers after perpetual motion, how many vain chimeras have you pursued? Go and take your place with the alchemists.”
         — Leonardo da Vinci, 1494